Effective dehydrogenation of 2-pyridylmethanol derivatives catalyzed by an iron complex.
Chem Commun (Camb)
; 50(59): 7941-4, 2014 Jul 28.
Article
em En
| MEDLINE
| ID: mdl-24740678
ABSTRACT
An unprecedented iron complex-catalyzed dehydrogenation of alcohols was achieved using CpFe(CO)2Cl with a base or CpFe(CO)(Py)(Ph) as a catalyst without sacrificing the hydrogen acceptors. This reaction effectively (up to TON 67,000) converted 2-pyridylmethanol derivatives to the corresponding ketones or aldehydes. The mechanistic study is also discussed.
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MEDLINE
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En
Ano de publicação:
2014
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Article