Metal-organic framework@microporous organic network: hydrophobic adsorbents with a crystalline inner porosity.
J Am Chem Soc
; 136(19): 6786-9, 2014 May 14.
Article
em En
| MEDLINE
| ID: mdl-24786337
ABSTRACT
This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.
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MEDLINE
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En
Ano de publicação:
2014
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Article