The mixed gold-palladium polyoxo-noble-metalate [NaAu(III)4Pd(II)8O8(AsO4)8](11-).

Izarova, Natalya V; Kondinski, Aleksandar; Vankova, Nina; Heine, Thomas; Jäger, Patrick; Schinle, Florian; Hampe, Oliver; Kortz, Ulrich

Izarova, Natalya V; Kondinski, Aleksandar; Vankova, Nina; Heine, Thomas; Jäger, Patrick; Schinle, Florian; Hampe, Oliver; Kortz, Ulrich.

Afiliação

Izarova NV; Jacobs University, School of Engineering and Science, P.O. Box 750561, 28725 Bremen (Germany), Fax: (+49) 421-200-3229; Current address: Peter-Grünberg-Institut, PGI-6, Forschungszentrum Jülich, 52425 Jülich (Germany), On leave from Nikolaev Institute of Inorganic Chemistry, Prospekt Lavrentyeva 3, 630090 Novosibirsk (Russia).

Chemistry ; 20(28): 8556-60, 2014 Jul 07.

Article em En | MEDLINE | ID: mdl-24898874

ABSTRACT

ABSTRACT

The first fully inorganic, discrete gold-palladium-oxo complex [NaAu(III) 4 Pd(II) 8 O8 (AsO4 )8 ](11-) has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.

Palavras-chave

density functional calculations; gold; mass spectrometry; palladium; polyoxometalates

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article

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