Tetrasilane-bridged bicyclo[4.1.0]heptasil-1(6)-ene.
J Am Chem Soc
; 136(37): 12896-8, 2014 Sep 17.
Article
em En
| MEDLINE
| ID: mdl-25168430
ABSTRACT
Tetrasilane-bridged bicyclo[4.1.0]heptasil-1(6)-ene 1 was synthesized by the reduction of 1,1,2,2-tetrachlorocyclohexasilane 2 in 12% yield as red-orange crystals. The structure and properties of 1 were studied by spectroscopy, X-ray crystallography, and theoretical calculations. The linkage of the cyclotrisilene moiety with two tetrasilane chains with tert-butyl groups remarkably affects its structure and (29)Si NMR spectrum.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article