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[Au7](3+): a missing link in the four-electron gold cluster family.
Shichibu, Yukatsu; Zhang, Mingzhe; Kamei, Yutaro; Konishi, Katsuaki.
Afiliação
  • Shichibu Y; Graduate School of Environmental Science and ‡Faculty of Environmental Earth Science, Hokkaido University , North 10 West 5, Sapporo 060-0810 Japan.
J Am Chem Soc ; 136(37): 12892-5, 2014 Sep 17.
Article em En | MEDLINE | ID: mdl-25184446
Ligand-stabilized ultrasmall gold clusters offer a library of diverse geometrical and electronic structures. Among them, clusters with four valence electrons form an exceptional but interesting family because of their unique geometrical structures and optical properties. Here, we report a novel diphosphine-ligated four-electron Au7 cluster (2). In good agreement with previous theoretical predictions, 2 has a "core+one" structure to exhibit a prolate shape. The absorption spectrum showed an isolated band, similar to the spectra of Au6 and Au8 clusters with "core+two" structures. TD-DFT studies demonstrated that the attachment of only one gold atom to a polyhedral core is sufficient to generate unique electronic structures and characteristic absorptions. The present result fills the missing link between Au6 and Au8 in the four-electron cluster family, showing that the HOMO-LUMO gap increases with increasing nuclearity in the case of the tetrahedron-based "core+exo" clusters.

Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2014 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2014 Tipo de documento: Article