Air stable NHCs: a study of stereoelectronics and metallorganic catalytic activity.
Chem Commun (Camb)
; 51(1): 74-6, 2015 Jan 04.
Article
em En
| MEDLINE
| ID: mdl-25317833
ABSTRACT
The air stable NHC IPrBr is reported. A stereoelectronic study of IPrBr and its similarly stable relative IMesBr demonstrates metal complex specific changes in NHC donicity versus the ubiquitous IPr and IMes. Application to a Suzuki coupling and an iridium transfer hydrogenation gives superior outcomes using IPrBr and IMesBr.
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MEDLINE
Idioma:
En
Ano de publicação:
2015
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Article