Oxidative photoredox-catalytic activation of aliphatic nucleophiles for C(sp(3))-C(sp(2)) cross-coupling reactions.
Angew Chem Int Ed Engl
; 53(49): 13326-8, 2014 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-25324184
ABSTRACT
In the light you will find the road (Led Zeppelin) Visible-light photoredox catalysis leads the way in overcoming the reactivity limitations of alkyl nucleophiles in cross-coupling reactions. Iridium-triggered oxidative photoredox activation of alkyltrifluoroborate or carboxylic acids affords alkyl radicals, which undergo nickel-catalyzed cross-coupling reactions.
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MEDLINE
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En
Ano de publicação:
2014
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Article