Electrophilic amination of fluoroalkyl groups on azodicarboxylate derivatives.
J Org Chem
; 80(3): 1964-71, 2015 Feb 06.
Article
em En
| MEDLINE
| ID: mdl-25565083
ABSTRACT
The formation of an NCF3 bond or an NCF2R bond still remains scarce. An efficient direct electrophilic amination of fluoroalkyl groups was developed. Difluoroenoxysilanes reacted easily on azodicarboxylate derivatives. These results led to a novel family of NCF3 and NCF2 hydrazine derivatives.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Compostos Azo
/
Hidrazinas
/
Hidrocarbonetos Fluorados
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article