Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu(I) fragments.
Chem Commun (Camb)
; 51(14): 2893-5, 2015 Feb 18.
Article
em En
| MEDLINE
| ID: mdl-25582612
ABSTRACT
A simple and straightforward synthesis of a new linear trinuclear Cu(I) cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu3 precursor with En ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on η(1)-coordination of the E2 ligands or one-dimensional coordination polymers featuring σ-1,3-bridging E5 rings, respectively.
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MEDLINE
Idioma:
En
Ano de publicação:
2015
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Article