A reversible two-electron redox system involving a divalent lead species.
Chem Commun (Camb)
; 51(22): 4674-6, 2015 Mar 18.
Article
em En
| MEDLINE
| ID: mdl-25692187
ABSTRACT
Reduction of THF-stabilized plumbacyclopentadienylidene with lithium afforded dilithioplumbole. On the other hand, oxidation of the dilithioplumbole provided the starting plumbacyclopentadienylidene. This is the unprecedented example of a reversible interconversion between group 14 M(II) and its dianionic species bearing organic substituents.
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MEDLINE
Idioma:
En
Ano de publicação:
2015
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Article