A tetranuclear copper cluster-based MOF with sulfonate-carboxylate ligands exhibiting high proton conduction properties.

Meng, Xing; Song, Shu-Yan; Song, Xue-Zhi; Zhu, Min; Zhao, Shu-Na; Wu, Lan-Lan; Zhang, Hong-Jie

Meng, Xing; Song, Shu-Yan; Song, Xue-Zhi; Zhu, Min; Zhao, Shu-Na; Wu, Lan-Lan; Zhang, Hong-Jie.

Afiliação

Meng X; State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625, Renmin Street, Changchun 130022, P. R. China. songsy@ciac.ac.cn hongjie@ciac.ac.cn.

Chem Commun (Camb) ; 51(38): 8150-2, 2015 May 11.

Article em En | MEDLINE | ID: mdl-25872974

ABSTRACT

ABSTRACT

A tetranuclear copper cluster-based MOF with sulfonate-carboxylate ligands has been synthesized. It possesses one-dimensional irregular channels lined with sulfonate, carboxylate, and DMF molecules, which show a high proton conductivity of 7.4 × 10(-4) S cm(-1) at 95 °C and 95% relative humidity.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article