Chemically and electrochemically induced expansion and contraction of a ferrocene rotor.
Chem Commun (Camb)
; 51(38): 8161-4, 2015 May 11.
Article
em En
| MEDLINE
| ID: mdl-25873268
ABSTRACT
A 2,2'-bipyridine-appended ferrocene rotor, 1,1'-di(5-yl-ethynyl-2,2'-bipyridine)ferrocene, can be switched from a folded/stacked (syn) conformation to an extended/unstacked (anti) conformation by the addition of [Cu(CH3CN)4](PF6) and 6,6'-dimesityl-2,2'-bipyridine. This extension and contraction process was completely reversible and could be triggered either chemically or electrochemically.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
2,2'-Dipiridil
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Compostos Ferrosos
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Técnicas Eletroquímicas
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article