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Fluorinated Alcohols as Activators for the Solvent-Free Chemical Fixation of Carbon Dioxide into Epoxides.
Gennen, Sandro; Alves, Margot; Méreau, Raphaël; Tassaing, Thierry; Gilbert, Bernard; Detrembleur, Christophe; Jerome, Christine; Grignard, Bruno.
Afiliação
  • Gennen S; Center for Education and Research on Macromolecules (CERM), Chemistry Department, B6a, University of Liège allée du 6 août, 4000 Liege (Belgium).
  • Alves M; Institut des Sciences Moléculaires (ISM), UMR5255 CNRS, Université de Bordeaux, 351 Cours de la libération, 33405 Talence Cedex (France).
  • Méreau R; Institut des Sciences Moléculaires (ISM), UMR5255 CNRS, Université de Bordeaux, 351 Cours de la libération, 33405 Talence Cedex (France).
  • Tassaing T; Institut des Sciences Moléculaires (ISM), UMR5255 CNRS, Université de Bordeaux, 351 Cours de la libération, 33405 Talence Cedex (France).
  • Gilbert B; Chemistry Department, B6C, University of Liège allée du 6 août, 4000 Liege (Belgium). b.gilbert@ulg.ac.be.
  • Detrembleur C; Center for Education and Research on Macromolecules (CERM), Chemistry Department, B6a, University of Liège allée du 6 août, 4000 Liege (Belgium). christophe.detrembleur@ulg.ac.be.
  • Jerome C; Center for Education and Research on Macromolecules (CERM), Chemistry Department, B6a, University of Liège allée du 6 août, 4000 Liege (Belgium). c.jerome@ulg.ac.be.
  • Grignard B; Center for Education and Research on Macromolecules (CERM), Chemistry Department, B6a, University of Liège allée du 6 août, 4000 Liege (Belgium).
ChemSusChem ; 8(11): 1845-9, 2015 Jun 08.
Article em En | MEDLINE | ID: mdl-25951520
ABSTRACT
The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2 /epoxides coupling.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Dióxido de Carbono / Álcoois / Compostos de Epóxi / Halogenação Idioma: En Ano de publicação: 2015 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Dióxido de Carbono / Álcoois / Compostos de Epóxi / Halogenação Idioma: En Ano de publicação: 2015 Tipo de documento: Article