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A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics.
Wang, Yanlan; Deyris, Pierre-Alexandre; Caneque, Tatiana; Blanchard, Florent; Li, Yanling; Bigi, Franca; Maggi, Raimondo; Blanchard, Sebastien; Maestri, Giovanni; Malacria, Max.
Afiliação
  • Wang Y; ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France).
  • Deyris PA; ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France).
  • Caneque T; ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France).
  • Blanchard F; ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France).
  • Li Y; UPMC Sorbonne Universités, IPCM (UMR CNRS 7201), 4 place Jussieu, C. 229, 75005 Paris (France).
  • Bigi F; Università degli Studi di Parma, Dipartimento di Chimica, 17A Parco Area delle Scienze, 43124 Parma (Italy).
  • Maggi R; Università degli Studi di Parma, Dipartimento di Chimica, 17A Parco Area delle Scienze, 43124 Parma (Italy).
  • Blanchard S; UPMC Sorbonne Universités, IPCM (UMR CNRS 7201), 4 place Jussieu, C. 229, 75005 Paris (France).
  • Maestri G; ICSN CNRS (UPR 2301), 1 Av. de la Terrasse, Bat. 27, 91198 Gif s/Yvette (France). giovanni.maestri@unipr.it.
  • Malacria M; Università degli Studi di Parma, Dipartimento di Chimica, 17A Parco Area delle Scienze, 43124 Parma (Italy). giovanni.maestri@unipr.it.
Chemistry ; 21(35): 12271-4, 2015 Aug 24.
Article em En | MEDLINE | ID: mdl-26149891
ABSTRACT
A simple synthetic method allows the one-pot assembly of C3 -symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article
Texto completo
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XML
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article