Sodium-Naphthalenide-Driven Synthesis of Base-Metal Nanoparticles and Follow-up Reactions.
Angew Chem Int Ed Engl
; 54(34): 9866-70, 2015 Aug 17.
Article
em En
| MEDLINE
| ID: mdl-26190645
ABSTRACT
Mo(0), W(0), Fe(0), Ru(0), Re(0), and Zn(0) nanoparticlesessentially base metalsare prepared as a general strategy by a sodium naphthalenide ([NaNaph])-driven reduction of simple metal chlorides in ethers (1,2-dimethoxyethane (DME), tetrahydrofuran (THF)). All the nanoparticles have diameters ≤10â
nm, and they can be obtained either as powder samples or long-term stable suspensions. Direct follow-up reactions (e.g., Mo(0)+S8, FeCl3+AsCl3, ReCl5+MoCl5), moreover, allow the preparation of MoS2, FeAs2, or Re4Mo nanoparticles of similar size as the pristine metals (≤10â
nm).
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MEDLINE
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Ano de publicação:
2015
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Article