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Lanthanide luminescent logic gate mimics in soft matter: [H(+)] and [F(-)] dual-input device in a polymer gel with potential for selective component release.
Bradberry, Samuel J; Byrne, Joseph P; McCoy, Colin P; Gunnlaugsson, Thorfinnur.
Afiliação
  • Bradberry SJ; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie.
  • Byrne JP; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie.
  • McCoy CP; School of Pharmacy, Queen's University Belfast, Belfast, BT9 7BL, UK.
  • Gunnlaugsson T; School of Chemistry and Trinity Biomedical Sciences Institute (TBSI), Trinity College Dublin, 152 - 160 Pearse Street, Dublin 2, Ireland. gunnlaut@tcd.ie bradbers@tcd.ie.
Chem Commun (Camb) ; 51(92): 16565-8, 2015 Nov 28.
Article em En | MEDLINE | ID: mdl-26421327
ABSTRACT
The non-covalent incorporation of responsive luminescent lanthanide, Ln(III), complexes with orthogonal outputs from Eu(III) and Tb(III) in a gel matrix allows for in situ logic operation with colorimetric outputs. Herein, we report an exemplar system with two inputs ([H(+)] and [F(-)]) within a p(HEMA-co-MMA) polymer organogel acting as a dual-responsive device and identify future potential for such systems.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article