Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu-thate(III)]-di-µ-iodido] dihydrate].
Acta Crystallogr E Crystallogr Commun
; 71(Pt 11): 1352-5, 2015 Nov 01.
Article
em En
| MEDLINE
| ID: mdl-26594509
ABSTRACT
A new organic-inorganic hybrid material, {(C7H10NO)[BiI4]·2H2O} n , has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI6] octa-hedra sharing edges. The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing. The p-anisidinium cations and the water mol-ecules are located in the voids of the anionic sublattice. The cations are linked to each other through N-Hâ¯O hydrogen bonds with the water mol-ecules, and also through weaker N-Hâ¯I inter-actions to the anionic inorganic layers.
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MEDLINE
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En
Ano de publicação:
2015
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Article