A High-Rate V2 O5 Hollow Microclew Cathode for an All-Vanadium-Based Lithium-Ion Full Cell.

ABSTRACT

V2O5 hollow microclews (V2O5-HMs) have been fabricated through a facile solvothermal method with subsequent calcination. The synthesized V2O5-HMs exhibit a 3D hierarchical structure constructed by intertangled nanowires, which could realize superior ion transport, good structural stability, and significantly improved tap density. When used as the cathodes for lithium-ion batteries (LIBs), the V2O5-HMs deliver a high capacity (145.3 mAh g(-1)) and a superior rate capability (94.8 mAh g(-1) at 65 C). When coupled with a lithiated Li3VO4 anode, the all-vanadium-based lithium-ion full cell exhibits remarkable cycling stability with a capacity retention of 71.7% over 1500 cycles at 6.7 C. The excellent electrochemical performance demonstrates that the V2O5-HM is a promising candidate for LIBs. The insight obtained from this work also provides a novel strategy for assembling 1D materials into hierarchical microarchitectures with anti-pulverization ability, excellent electrochemical kinetics, and enhanced tap density.