Synthesis of vinylphosphines and unsymmetric diphosphines: iron-catalyzed selective hydrophosphination reaction of alkynes and vinylphosphines with secondary phosphines.
Chem Commun (Camb)
; 52(15): 3163-6, 2016 Feb 21.
Article
em En
| MEDLINE
| ID: mdl-26805625
ABSTRACT
Iron complex-catalyzed regioselective single hydrophosphination of terminal arylalkynes with secondary phosphines was achieved. Unsymmetric 1,2-bis(phosphino)ethanes with different phosphino groups were obtained by using our catalytic systems. The structures of the obtained vinylphosphine, unsymmetric 1,2-bis(phosphino)ethane, and iron catalyst precursors were confirmed by single crystal X-ray diffraction studies.
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MEDLINE
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En
Ano de publicação:
2016
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Article