Hydrogen evolution catalyzed by a cobalt complex containing an asymmetric Schiff-base ligand.
Dalton Trans
; 45(13): 5430-3, 2016 Apr 07.
Article
em En
| MEDLINE
| ID: mdl-26948148
ABSTRACT
A cobalt(iii) complex containing an asymmetric Schiff-base ligand has been found to be active for proton reduction. Catalysis occurs at -1.2 V vs. Fc(+)/Fc (0.56 V vs. NHE), resulting in an overpotential of 350 mV. Additionally, the complex is active with a turnover frequency of 420 s(-1). An enhancement in activity is observed upon addition of water.
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MEDLINE
Idioma:
En
Ano de publicação:
2016
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Article