Copper-catalyzed carboxylation reactions using carbon dioxide.
Org Biomol Chem
; 14(15): 3666-76, 2016 Apr 12.
Article
em En
| MEDLINE
| ID: mdl-27035704
ABSTRACT
Carbon dioxide (CO2), as a waste of manufacture, is a cheap and abundant C1 source. Utilization of CO2 for synthesis of carboxylic acids has been developed. Transition-metal complexes play a key role in catalytic carboxylation reactions employing CO2. This review summarizes recent advances in copper-catalyzed carboxylation reactions using CO2. The contents are arranged based on various substrates organometallic reagents, aryl iodides, sodium sulfinates, terminal alkynes, arenes, heteroarenes, and unsaturated substrates.
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MEDLINE
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En
Ano de publicação:
2016
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Article