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Response to Comment on "Cycling Li-O2 batteries via LiOH formation and decomposition".
Liu, Tao; Kim, Gunwoo; Carretero-González, Javier; Castillo-Martínez, Elizabeth; Grey, Clare P.
Afiliação
  • Liu T; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
  • Kim G; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. Cambridge Graphene Centre, University of Cambridge, Cambridge CB3 0FA, UK.
  • Carretero-González J; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
  • Castillo-Martínez E; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
  • Grey CP; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. Cambridge Graphene Centre, University of Cambridge, Cambridge CB3 0FA, UK. cpg27@cam.ac.uk.
Science ; 352(6286): 667, 2016 May 06.
Article em En | MEDLINE | ID: mdl-27151859
We described a lithium-oxygen (Li-O2) battery comprising a graphene electrode, a dimethoxyethane-based electrolyte, and H2O and lithium iodide (LiI) additives, lithium hydroxide (LiOH) being the predominant discharge product. We demonstrate, in contrast to the work of Shen et al., that the chemical reactivity between LiOH and the triiodide ion (I3 (-)) to form IO3 (-) indicates that LiOH can be removed on charging; the electrodes do not clog, even after multiple cycles, confirming that solid products are reversibly removed.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article