Production of Structural Colors with High Contrast and Wide Viewing Angles from Assemblies of Polypyrrole Black Coated Polystyrene Nanoparticles.
ACS Appl Mater Interfaces
; 8(25): 16289-95, 2016 Jun 29.
Article
em En
| MEDLINE
| ID: mdl-27322393
ABSTRACT
Structural color with wide viewing angles has enormous potential applications in pigment, ink formulation, displays, and sensors. However, colors obtained from colloidal assemblies with low refractive index contrast or without black additives typically appear pale. Here, we prepare polypyrrole (PPy) black coated polystyrene (PS) nanoparticles and demonstrate well-defined colors with high color contrast and wide viewing angles under ambient light. Depending on the loading of pyrrole during polymerization, PPy nanogranules of different sizes and coverages are grafted to the surface of PS nanoparticles. The bumpy particles can self-assemble into quasi-amorphous arrays, resulting in low angle dependent structure colors under ambient light. The color can be tuned by the size of the PS nanoparticles, and the presence of the PPy black on PS nanoparticles enhances the color contrast by suppressing incoherent and multiple scattering.
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MEDLINE
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En
Ano de publicação:
2016
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Article