Classical/Non-classical Polyoxometalate Hybrids.
Chemistry
; 22(45): 16052-16056, 2016 Nov 02.
Article
em En
| MEDLINE
| ID: mdl-27617918
ABSTRACT
Two polyanions [SeI V2 PdII4 WVI14 O56 H]11- and [SeI V4 PdII4 WVI28 O108 H12 ]12- are the first hybrid polyoxometalates in which classical (Groupâ
5/6 metal based) and non-classical (late transition-metal based) polyoxometalate units are joined. Requiring no supporting groups, this co-condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM-PdII coordination complexes and the young subclass of polyoxopalladates. Solid-state, solution, and gas-phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
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MEDLINE
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En
Ano de publicação:
2016
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Article