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Ultrafast Singlet Energy Transfer in Porphyrin Dyads.
Dekkiche, Hervé; Buisson, Antoine; Langlois, Adam; Karsenti, Paul-Ludovic; Ruhlmann, Laurent; Harvey, Pierre D; Ruppert, Romain.
Afiliação
  • Dekkiche H; Institut de Chimie, UMR 7177 du CNRS, Université de Strasbourg , 4 rue Blaise Pascal, 67000 Strasbourg, France.
  • Buisson A; Département de Chimie, Université de Sherbrooke , Sherbrooke, Quebec J1K2R1, Canada.
  • Langlois A; Département de Chimie, Université de Sherbrooke , Sherbrooke, Quebec J1K2R1, Canada.
  • Karsenti PL; Département de Chimie, Université de Sherbrooke , Sherbrooke, Quebec J1K2R1, Canada.
  • Ruhlmann L; Institut de Chimie, UMR 7177 du CNRS, Université de Strasbourg , 4 rue Blaise Pascal, 67000 Strasbourg, France.
  • Harvey PD; Département de Chimie, Université de Sherbrooke , Sherbrooke, Quebec J1K2R1, Canada.
  • Ruppert R; Institut de Chimie, UMR 7177 du CNRS, Université de Strasbourg , 4 rue Blaise Pascal, 67000 Strasbourg, France.
Inorg Chem ; 55(20): 10329-10336, 2016 Oct 17.
Article em En | MEDLINE | ID: mdl-27709919
ABSTRACT
A weakly fluorescent Pt-bridged dyad composed of zinc(II) porphyrin (Zn; donor) and free base (Fb; acceptor) has been designed and exhibits an ultrafast singlet energy transfer between porphyrins. The use of larger atoms within the central linker significantly increases the MO coupling between the two chromophores and inherently the electronic communication.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article