Metal- and base-free reductive coupling reaction of P(O)-H with aryl/alkyl sulfonyl chlorides: a novel protocol for the construction of P-S-C bonds.
Org Biomol Chem
; 15(3): 545-549, 2017 Jan 18.
Article
em En
| MEDLINE
| ID: mdl-27934999
ABSTRACT
Novel and efficient synthesis of S-aryl/alkyl phosphinothioates from P(O)-H and aryl/alkyl sulfonyl chlorides under metal- and base-free conditions is described. This reaction provides an alternative strategy for the construction of P-S-C bonds in moderate to excellent yields. Moreover, this method can be readily applied to gram-scale preparation.
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MEDLINE
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En
Ano de publicação:
2017
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Article