Tetragonal to Cubic Transformation of SiO2-Stabilized ZrO2 Polymorph through Dysprosium Substitutions.
Inorg Chem
; 56(3): 1273-1281, 2017 Feb 06.
Article
em En
| MEDLINE
| ID: mdl-28060492
ABSTRACT
Partially stabilized tetragonal zirconia (t-ZrO2) is of particular interest for hard tissue replacements. Aging-related failures of the ceramic associated with the gradual transformation from t-ZrO2 to m-ZrO2 (monoclinic zirconia) can lead to its premature removal from the implant site. In addition, monitoring the satisfactory performance of the implant throughout its lifespan without invasive techniques is a challenging task. The magnetic resonance imaging (MRI) contrast ability of dysprosium (Dy3+) is well-established. To this aim, varied levels of Dy3+ additions in the ZrO2-SiO2 binary oxide system were explored. The results indicate the effective role of Dy3+ in the formation of thermally and mechanically stable c-ZrO2 (cubic zirconia) phase at higher temperatures. The presence of SiO2 influenced the t-ZrO2 stabilization, whereas Dy3+ tends to occupy the ZrO2 lattice sites to induce c-ZrO2 transition. Magnetic and MRI tests displayed the commendable contrast ability of Dy3+ stabilized ZrO2-SiO2 binary systems. Nanoindentation results demonstrate a remarkable enhancement of the mechanical properties.
Texto completo:
1
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article