Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles.

Llevot, A; Monney, B; Sehlinger, A; Behrens, S; Meier, M A R

Llevot, A; Monney, B; Sehlinger, A; Behrens, S; Meier, M A R.

Afiliação

Llevot A; Karlsruhe Institute of Technology (KIT), Institute of Organic Chemistry (IOC), Materialwissenschaftliches Zentrum MZE, Straße am Forum 7, 76131 Karlsruhe, Germany. m.a.r.meier@kit.edu.

Chem Commun (Camb) ; 53(37): 5175-5178, 2017 May 04.

Article em En | MEDLINE | ID: mdl-28439582

ABSTRACT

ABSTRACT

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article