Triphenylamine-Functionalized Silsesquioxane-Based Hybrid Porous Polymers: Tunable Porosity and Luminescence for Multianalyte Detection.
Chemistry
; 23(54): 13465-13473, 2017 Sep 27.
Article
em En
| MEDLINE
| ID: mdl-28695636
ABSTRACT
A series of hybrid luminescent porous polymers (HLPPs) are synthesized through Friedel-Crafts reactions by tuning the molar ratio of triphenylamine (TPA) to octavinylsilsesquioxane (OVS). The synthesized HLPPs exhibit high Brunauer-Emmett-Teller surface areas up to 841±10â
m2 g-1 , high thermal stability with decomposition temperatures (Td at 5â
wt %) up to 440 °C in air, and strong blue-violet luminescence at approximately 450â
nm. The porosities and luminescent properties of the HLPPs, including emission wavelength, intensity, fluorescence quantum yield, and monochromaticity, can be tuned easily by modulating the molar ratio of TPA to OVS. In addition, the polymers may serve as excellent fluorescent probes for multianalyte detection, with high fluorescence quenching coefficients (KSV ) of 8900 and 4400 m-1 for Fe3+ and Cu2+ , respectively.
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Base de dados:
MEDLINE
Tipo de estudo:
Diagnostic_studies
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article