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Carbonyl Iron Powder: A Reagent for Nitro Group Reductions under Aqueous Micellar Catalysis Conditions.
Lee, Nicholas R; Bikovtseva, Agata A; Cortes-Clerget, Margery; Gallou, Fabrice; Lipshutz, Bruce H.
Afiliação
  • Lee NR; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Bikovtseva AA; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Cortes-Clerget M; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
  • Gallou F; Chemical & Analytical Development, Novartis Pharma AG , 4056 Basel, Switzerland.
  • Lipshutz BH; Department of Chemistry and Biochemistry, University of California , Santa Barbara, California 93106, United States.
Org Lett ; 19(24): 6518-6521, 2017 12 15.
Article em En | MEDLINE | ID: mdl-29206473
ABSTRACT
An especially mild, safe, efficient, and environmentally responsible reduction of aromatic and heteroaromatic nitro-group-containing educts is reported that utilizes very inexpensive carbonyl iron powder (CIP), a highly active commercial grade of iron powder. These reductions are conducted in the presence of nanomicelles composed of TPGS-750-M in water, a recyclable aqueous micellar reaction medium. This new technology also shows broad scope and scalability and presents opportunities for multistep one-pot sequences involving this reducing agent.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article