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23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6].
Vorotnikova, Natalya A; Vorotnikov, Yuri A; Novozhilov, Igor N; Syrokvashin, Mikhail M; Nadolinny, Vladimir A; Kuratieva, Natalia V; Benoit, David M; Mironov, Yuri V; Walton, Richard I; Clarkson, Guy J; Kitamura, Noboru; Sutherland, Andrew J; Shestopalov, Michael A; Efremova, Olga A.
Afiliação
  • Vorotnikova NA; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Vorotnikov YA; Scientific Institute of Clinical and Experimental Lymphology-branch of ICG SB RAS , 2 Timakova str., 630060 Novosibirsk, Russian Federation.
  • Novozhilov IN; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Syrokvashin MM; Scientific Institute of Clinical and Experimental Lymphology-branch of ICG SB RAS , 2 Timakova str., 630060 Novosibirsk, Russian Federation.
  • Nadolinny VA; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Kuratieva NV; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Benoit DM; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Mironov YV; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Walton RI; Novosibirsk State University , 2 Pirogova str., 630090 Novosibirsk, Russian Federation.
  • Clarkson GJ; School of Mathematics and Physical Sciences, University of Hull , Cottingham Road, Hull, HU6 7RX, United Kingdom.
  • Kitamura N; Nikolaev Institute of Inorganic Chemistry SB RAS , 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation.
  • Sutherland AJ; Novosibirsk State University , 2 Pirogova str., 630090 Novosibirsk, Russian Federation.
  • Shestopalov MA; Department of Chemistry, University of Warwick , Coventry, CV4 7AL, United Kingdom.
  • Efremova OA; Department of Chemistry, University of Warwick , Coventry, CV4 7AL, United Kingdom.
Inorg Chem ; 57(2): 811-820, 2018 Jan 16.
Article em En | MEDLINE | ID: mdl-29271200
ABSTRACT
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e- cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article