Efficient synthesis of a 6-deoxy-talose containing tetrasccharide found in Franconibacter helveticus LMG23732T.
Carbohydr Res
; 460: 57-65, 2018 May 02.
Article
em En
| MEDLINE
| ID: mdl-29525186
ABSTRACT
Synthesis of the 6-deoxy-talose (6-dTal) containing tetrasaccharide, naturally found in Franconibacter helveticus LMG23732T, has been described. The synthetic method utilized an allyloxyethylidene group for protecting the 1-OH and 2-OH groups of rhamnopyranose and a redox reaction for synthesizing 6-deoxy talose, which eventually formed a disaccharide containing α-Glcp-(1â2)-6dTalp configured glycosidic bonds using a [2 + 2] synthetic strategy.
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Base de dados:
MEDLINE
Assunto principal:
Polissacarídeos Bacterianos
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Lipopolissacarídeos
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Enterobacteriaceae
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article