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Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction.
Burks, Dalton B; Davis, Shakeyia; Lamb, Robert W; Liu, Xuan; Rodrigues, Roberta R; Liyanage, Nalaka P; Sun, Yujie; Webster, Charles Edwin; Delcamp, Jared H; Papish, Elizabeth T.
Afiliação
  • Burks DB; University of Alabama (UA), Department of Chemistry, Shelby Hall, Tuscaloosa, AL 35487, USA. etpapish@ua.edu.
  • Davis S; University of Mississippi, Department of Chemistry and Biochemistry, Coulter Hall, University, MS 38677, USA. delcamp@olemiss.edu.
  • Lamb RW; Mississippi State University, Department of Chemistry, Hand Chemical Lab, Mississippi State, MS 39762, USA. ewebster@chemistry.msstate.edu.
  • Liu X; Utah State University, Department of Chemistry and Biochemistry, Widtsoe Hall, Logan, UT 84322, USA.
  • Rodrigues RR; University of Mississippi, Department of Chemistry and Biochemistry, Coulter Hall, University, MS 38677, USA. delcamp@olemiss.edu.
  • Liyanage NP; University of Mississippi, Department of Chemistry and Biochemistry, Coulter Hall, University, MS 38677, USA. delcamp@olemiss.edu.
  • Sun Y; Utah State University, Department of Chemistry and Biochemistry, Widtsoe Hall, Logan, UT 84322, USA.
  • Webster CE; Mississippi State University, Department of Chemistry, Hand Chemical Lab, Mississippi State, MS 39762, USA. ewebster@chemistry.msstate.edu.
  • Delcamp JH; University of Mississippi, Department of Chemistry and Biochemistry, Coulter Hall, University, MS 38677, USA. delcamp@olemiss.edu.
  • Papish ET; University of Alabama (UA), Department of Chemistry, Shelby Hall, Tuscaloosa, AL 35487, USA. etpapish@ua.edu.
Chem Commun (Camb) ; 54(31): 3819-3822, 2018 Apr 12.
Article em En | MEDLINE | ID: mdl-29560991
ABSTRACT
The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(ii) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO2 reduction. The O- substituent appears essential for catalysis.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article