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Selective, Scalable Synthesis of C60-Fullerene/Indene Monoadducts Using a Microwave Flow Applicator.
Barham, Joshua P; Tanaka, Satoko; Koyama, Emiko; Ohneda, Noriyuki; Okamoto, Tadashi; Odajima, Hiromichi; Sugiyama, Jun-Ichi; Norikane, Yasuo.
Afiliação
  • Barham JP; National Institute of Advanced Industrial Science and Technology , Tsukuba Central 5, 1-1-1 Higashi , Tsukuba , Ibaraki 305-8568 , Japan.
  • Tanaka S; SAIDA FDS, INC. , 143-10 Isshiki , Yaizu , Shizuoka 425-0054 , Japan.
  • Koyama E; National Institute of Advanced Industrial Science and Technology , Tsukuba Central 5, 1-1-1 Higashi , Tsukuba , Ibaraki 305-8568 , Japan.
  • Ohneda N; National Institute of Advanced Industrial Science and Technology , Tsukuba Central 5, 1-1-1 Higashi , Tsukuba , Ibaraki 305-8568 , Japan.
  • Okamoto T; SAIDA FDS, INC. , 143-10 Isshiki , Yaizu , Shizuoka 425-0054 , Japan.
  • Odajima H; SAIDA FDS, INC. , 143-10 Isshiki , Yaizu , Shizuoka 425-0054 , Japan.
  • Sugiyama JI; SAIDA FDS, INC. , 143-10 Isshiki , Yaizu , Shizuoka 425-0054 , Japan.
  • Norikane Y; National Institute of Advanced Industrial Science and Technology , Tsukuba Central 5, 1-1-1 Higashi , Tsukuba , Ibaraki 305-8568 , Japan.
J Org Chem ; 83(8): 4348-4354, 2018 04 20.
Article em En | MEDLINE | ID: mdl-29642704
ABSTRACT
The synergy of continuous processing and microwave heating technologies has unlocked scalable (g/h), safe and efficient reaction conditions for synthesis of fullerene/indene-based organic photovoltaic acceptor materials in a nonchlorinated solvent with levels of productivity unparalleled by previous syntheses. The microwave flow reactor sustains high temperature while employing short residence times, reaction conditions which uniquely allow the selective synthesis of fullerene/indene monoadducts. Design of experiments analysis revealed residence time as the most crucial factor for conversion and selectivity control.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article