Site-Directed Surface Derivatization of MCM-41: Use of High-Resolution Transmission Electron Microscopy and Molecular Recognition for Determining the Position of Functionality within Mesoporous Materials.
Angew Chem Int Ed Engl
; 37(19): 2719-2723, 1998 Oct 16.
Article
em En
| MEDLINE
| ID: mdl-29711606
ABSTRACT
The "staining" cluster-crown compound [Ru6 C(CO)14 (η6 -C6 H4 C10 H20 O6 )] verifies that the internal walls of mesoporous silica MCM-41 may be selectively functionalized with propylammonium groups (see picture). By the use of high-resolution transmission electron microscopy the presence and position of the cluster and also of the functional groups may be directly determined.
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MEDLINE
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En
Ano de publicação:
1998
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Article