Single-Crystalline UiO-67-Type Porous Network Stable to Boiling Water, Solvent Loss, and Oxidation.
Inorg Chem
; 57(11): 6198-6201, 2018 Jun 04.
Article
em En
| MEDLINE
| ID: mdl-29781597
ABSTRACT
With methylthio groups flanking the carboxyl groups, the 3,3',5,5'-tetrakis(methylthio)biphenyl dicarboxylate (TMBPD) linker forms a zirconium(IV) carboxylate porous framework featuring the topology of the UiO-67 prototype, i.e., with a face-centered-cubic array of the Zr6O4(OH)4 clusters. Thioether functionalization proves valuable because the ZrTMBPD crystal is found to be exceptionally stable not only upon long-term exposure to air but also in boiling water and a broad range of pH conditions. The hydrophobicity of the metal-organic framework can also be tuned by simple H2O2 oxidation, as illustrated in the water contact-angle measurement of the pristine and H2O2-treated ZrTMBPD solid.
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MEDLINE
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En
Ano de publicação:
2018
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Article