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Core-Shell Crystals of Porous Organic Cages.
Jiang, Shan; Du, Yi; Marcello, Marco; Corcoran, Edward W; Calabro, David C; Chong, Samantha Y; Chen, Linjiang; Clowes, Rob; Hasell, Tom; Cooper, Andrew I.
Afiliação
  • Jiang S; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
  • Du Y; Corporate Strategic Research, ExxonMobil Research and Engineering Company, 1545 U.S. Highway 22, Annandale, NJ, 08801, USA.
  • Marcello M; Institute of Integrative Biology, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK.
  • Corcoran EW; Corporate Strategic Research, ExxonMobil Research and Engineering Company, 1545 U.S. Highway 22, Annandale, NJ, 08801, USA.
  • Calabro DC; Corporate Strategic Research, ExxonMobil Research and Engineering Company, 1545 U.S. Highway 22, Annandale, NJ, 08801, USA.
  • Chong SY; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
  • Chen L; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
  • Clowes R; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
  • Hasell T; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
  • Cooper AI; Department of Chemistry, Materials Innovation Factory, University of Liverpool, Liverpool, L69 7ZD, UK.
Angew Chem Int Ed Engl ; 57(35): 11228-11232, 2018 Aug 27.
Article em En | MEDLINE | ID: mdl-29888555
ABSTRACT
The first examples of core-shell porous molecular crystals are described. The physical properties of the core-shell crystals, such as surface hydrophobicity, CO2 /CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core-shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article