An organocatalyst bound α-aminoalkyl radical intermediate for controlled aerobic oxidation of iminium ions.
Org Biomol Chem
; 16(28): 5081-5085, 2018 07 18.
Article
em En
| MEDLINE
| ID: mdl-29947387
ABSTRACT
A catalyst bound α-aminoalkyl radical intermediate from iminium is developed to control its formation and reactivity with aerobic oxygen. The influence of the catalyst was demonstrated via the ease of radical intermediate formation and its subsequent reactivity, including the first catalyst-controlled enantioselective aerobic oxidation with a chiral phosphite catalyst.
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MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article