Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water.
Molecules
; 23(8)2018 Jul 27.
Article
em En
| MEDLINE
| ID: mdl-30060516
ABSTRACT
We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.
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Base de dados:
MEDLINE
Assunto principal:
Compostos de Benzil
/
Clorofilídeos
/
Metano
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article