Facile Synthesis of a Stable Dihydroboryl {BH2 }- Anion.
Angew Chem Int Ed Engl
; 57(46): 15272-15275, 2018 Nov 12.
Article
em En
| MEDLINE
| ID: mdl-30238575
ABSTRACT
While the one-electron reduction of (CAACMe )BH2 Br (CAACMe =1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields a hydride-shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAACMe )BH2 ]- , which acts as a powerful boron nucleophile.
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MEDLINE
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En
Ano de publicação:
2018
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Article