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Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change.
Long, Jérôme; Basalov, Ivan V; Forosenko, Natalia V; Lyssenko, Konstantin A; Mamontova, Ekaterina; Cherkasov, Anton V; Damjanovic, Marko; Chibotaru, Liviu F; Guari, Yannick; Larionova, Joulia; Trifonov, Alexander A.
Afiliação
  • Long J; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Basalov IV; Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str, 630950, Nizhny Novgorod GSP-445, Russia.
  • Forosenko NV; Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str, 630950, Nizhny Novgorod GSP-445, Russia.
  • Lyssenko KA; Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilova str., 119334, Moscow, Russia.
  • Mamontova E; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Cherkasov AV; Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str, 630950, Nizhny Novgorod GSP-445, Russia.
  • Damjanovic M; Physikalisches Institut and Institute of Nanotechnology, Karlsruhe Institute of Technology, Wolfgang-Gaede-Strasse 1, 76131, Karlsruhe, Germany.
  • Chibotaru LF; Theory of Nanomaterials Group and INPAC, Katholieke Universiteit Leuven, Celesijnenlaan, 200F, Heverlee, B-3001, Belgium.
  • Guari Y; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Larionova J; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Trifonov AA; Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str, 630950, Nizhny Novgorod GSP-445, Russia.
Chemistry ; 25(2): 474-478, 2019 Jan 07.
Article em En | MEDLINE | ID: mdl-30376601
ABSTRACT
The synthesis, and magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands is reported. Magnetic investigations reveal a genuine single-molecule magnet (SMM) behavior, with out-of-phase signals up to 60 K, and tunable emission arising from the Schiff base ligands.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article