Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb<sub>14</sub>MgSb<sub>11</sub>.

Kunz Wille, Elizabeth L; Jo, Na Hyun; Fettinger, James C; Canfield, Paul C; Kauzlarich, Susan M

Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb₁₄MgSb₁₁.

Kunz Wille, Elizabeth L; Jo, Na Hyun; Fettinger, James C; Canfield, Paul C; Kauzlarich, Susan M.

Afiliação

Kunz Wille EL; Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, CA 95616, USA. smkauzlarich@ucdavis.edu.

Chem Commun (Camb) ; 54(92): 12946-12949, 2018 Nov 15.

Article em En | MEDLINE | ID: mdl-30379152

ABSTRACT

ABSTRACT

Large crystals of Yb14MgSb11 were grown through a Sn flux method. Magnetic susceptibility measurements yield an effective magnetic moment of 3.4(1) µB, revealing the presence of both divalent and trivalent Yb in Yb14MgSb11. Previously assumed to only contain Yb2+ as in Yb14MnSb11, the mixed valency demonstrates that Yb14MgSb11 is a Zintl phase.

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2018 Tipo de documento: Article