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A New Biscarbazole-Based Metal-Organic Framework for Efficient Host-Guest Energy Transfer.
Mu, Qianqian; Liu, Jingjuan; Chen, Weiben; Song, Xiaoyu; Liu, Xiaoting; Zhang, Xiaotao; Chang, Ze; Chen, Long.
Afiliação
  • Mu Q; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
  • Liu J; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
  • Chen W; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
  • Song X; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
  • Liu X; School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecular-Based Material Chemistry, Nankai University, Tianjin, 300350, P. R. China.
  • Zhang X; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
  • Chang Z; School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecular-Based Material Chemistry, Nankai University, Tianjin, 300350, P. R. China.
  • Chen L; Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072, P. R. China.
Chemistry ; 25(8): 1901-1905, 2019 Feb 06.
Article em En | MEDLINE | ID: mdl-30618074
ABSTRACT
A new metal-organic framework (MOF), [Zn6 L4 (Me2 NH2 + )4 ⋅3 H2 O] (1) was constructed based on [9, 9'-biscarbazole]-3, 3', 6, 6'-tetracarboxylic acid (H4 L) and Zn2+ ions. The porous framework and intense blue fluorescence of the MOF based on the biscarbazole moiety of the ligand could facilitate efficient host to guest energy transfer, which makes it an ideal platform for the tuning of luminescence.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article