Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties.

ABSTRACT

Two novel bismuth oxyfluoride nitrates, Bi2OF3(NO3) and Bi6O6F5(NO3), have been synthesized via hydrothermal reactions. Whereas Bi2OF3(NO3) crystallizes in the centrosymmetric (CS) hexagonal space group, P63/ m, Bi6O6F5(NO3) crystallizes in the polar noncentrosymmetric (NCS) trigonal space group, R3. The backbones of the title compounds reveal double layered structures composed of asymmetric BiF3(O/F)3 or BiO3F2 polyhedra and NO3 trigonal planar groups. The diffuse reflectance spectra indicate that Bi2OF3(NO3) and Bi6O6F5(NO3) contain wide band gaps of 3.5 and 4.0 eV, respectively. Powder second-harmonic generation (SHG) measurements suggest that NCS Bi6O6F5(NO3) is Type-I phase-matchable and has a large SHG response of ca. 3 times that of KH2PO4 (KDP). Electron localization function (ELF) analysis indicates that the large SHG efficiency of Bi6O6F5(NO3) is attributed to the synergistic effect of the alignment of NO3- trigonal planar groups and strong interactions between highly polarizable lone pair electrons on Bi3+ and π-delocalized electrons in NO3- groups. Bi2OF3(NO3) also exhibits a very good photocatalytic degradation efficiency of Rhodamine B (RhB) under the UV light irradiation.