Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds.
Angew Chem Int Ed Engl
; 58(13): 4405-4409, 2019 Mar 22.
Article
em En
| MEDLINE
| ID: mdl-30719809
ABSTRACT
The lability of B=B, B-P, and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2019
Tipo de documento:
Article