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Biomimetic Self-Assembly of CoII-Seamed Hexameric Metal-Organic Nanocapsules.
Hu, Xiangquan; Chai, Jie; Zhang, Chen; Lang, Jinxin; Kelley, Steven P; Feng, Sisi; Liu, Bin; Atwood, David A; Atwood, Jerry L.
Afiliação
  • Hu X; Department of Chemistry , University of Missouri-Columbia , Columbia Missouri 65211 , United States.
  • Chai J; Key Laboratory of Chemical Biology, Molecular Engineering of Ministry of Education, Institute of Molecular Science , Shanxi University , Taiyuan 030006 , China.
  • Zhang C; Department of Chemical and Biomolecular Engineering , North Carolina State University , Raleigh , North Carolina 27695 , United States.
  • Lang J; Department of Chemistry, School of Science , Xi'an Jiaotong University , Xi'an 710049 , P.R. China.
  • Kelley SP; Department of Chemistry , University of Missouri-Columbia , Columbia Missouri 65211 , United States.
  • Feng S; Key Laboratory of Chemical Biology, Molecular Engineering of Ministry of Education, Institute of Molecular Science , Shanxi University , Taiyuan 030006 , China.
  • Liu B; Key Laboratory of Chemical Biology, Molecular Engineering of Ministry of Education, Institute of Molecular Science , Shanxi University , Taiyuan 030006 , China.
  • Atwood DA; Department of Chemistry , University of Kentucky , Lexington , Kentucky 40506 , United States.
  • Atwood JL; Department of Chemistry , University of Missouri-Columbia , Columbia Missouri 65211 , United States.
J Am Chem Soc ; 141(23): 9151-9154, 2019 06 12.
Article em En | MEDLINE | ID: mdl-31083943
ABSTRACT
A CoII18L6 hexameric metal-organic nanocapsule (MONC) has been prepared and characterized using biomimetic self-assembly as the synthetic methodology. Akin to the biological behavior of zinc-finger proteins' release, uptake, and electrophilic substitution of Zn2+ ions, the assembly of this novel MONC has been accomplished by employing three sequential processes assembly of the framework, metal ion insertion, and metal exchange, resulting in the formation of the CoII18L6 hexameric MONC. In this work, inspired by the biological behavior of metalloproteins, rational control of multiple complex supramolecular self-assembly has been achieved.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Engenharia Química / Cobalto / Biomimética / Nanopartículas Metálicas Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Engenharia Química / Cobalto / Biomimética / Nanopartículas Metálicas Idioma: En Ano de publicação: 2019 Tipo de documento: Article