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A radical capture mechanism for immediate Csp2-H bond hydroxylation via a heterogeneous Cu-graphene catalyst.
Sun, Wei; Gao, Lingfeng; Zheng, Gengxiu.
Afiliação
  • Sun W; School of Chemistry and Chemical Engineering, University of Jinan, No. 336 West Road of Nan Xinzhuang, Jinan 250022, P. R. China. chm_zhenggx@ujn.edu.cn gaolf108@mail.ustc.edu.cn.
  • Gao L; School of Chemistry and Chemical Engineering, University of Jinan, No. 336 West Road of Nan Xinzhuang, Jinan 250022, P. R. China. chm_zhenggx@ujn.edu.cn gaolf108@mail.ustc.edu.cn.
  • Zheng G; School of Chemistry and Chemical Engineering, University of Jinan, No. 336 West Road of Nan Xinzhuang, Jinan 250022, P. R. China. chm_zhenggx@ujn.edu.cn gaolf108@mail.ustc.edu.cn.
Chem Commun (Camb) ; 55(61): 8915-8918, 2019 Aug 07.
Article em En | MEDLINE | ID: mdl-31259353
ABSTRACT
A radical capture mechanism via a synergistic heterogeneous Cu2O-rGO catalyst for Csp2-H bond immediate hydroxylation has been developed. This protocol suggests the involvement of a C-centered radical (˙C), generated through an O-centered radical (˙OH) initiated hydrogen atom transfer (HAT) process.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article