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Chemoselective Luche-Type Reduction of α,ß-Unsaturated Ketones by Magnesium Catalysis.
Jang, Yoon Kyung; Magre, Marc; Rueping, Magnus.
Afiliação
  • Jang YK; Institute of Organic Chemistry , RWTH Aachen University , Landoltweg 1 , 52074 Aachen , Germany.
  • Magre M; Institute of Organic Chemistry , RWTH Aachen University , Landoltweg 1 , 52074 Aachen , Germany.
  • Rueping M; Institute of Organic Chemistry , RWTH Aachen University , Landoltweg 1 , 52074 Aachen , Germany.
Org Lett ; 21(20): 8349-8352, 2019 Oct 18.
Article em En | MEDLINE | ID: mdl-31588757
ABSTRACT
The chemoselective reduction of α,ß-unsaturated ketones by use of an economic and readily available Mg catalyst has been developed. Excellent yields for a wide range of ketones have been achieved under mild reaction conditions, short times, and low catalyst loadings (0.2-0.5 mol %).

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article