Occurrence and leaching of silver in municipal sewage sludge in China.

ABSTRACT

Sewage treatment plants effectively remove silver (Ag) from sewage. Sewage sludge can therefore be important Ag sinks, polluting the environment with this element. In this work, we report a nation-wide survey on the Ag content of sewage sludge in China (0.23-19.02 mg kg-1, average 2.72 mg kg-1). Furthermore, we identify that sludge disposal represents an important Ag pollution source (84.48 tons in 2016) for the environment by estimating the national and provincial inventories of sludge-borne Ag in China. Also the positive correlations between the per capita gross domestic product (GDP)/provincial GDP and the content/mass loadings of Ag highlighted the impact of human activities on Ag pollution. In different samples, strong complexation of thiosulfate contributed to the highest leaching concentration (95.00-438.15 µg kg-1) and ratio (1.9-8.8%) of Ag, emphasizing the necessity of a long-term risk assessment for landfill and land application of sludge.