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Ag-modified Fe2O3 nanoparticles on a carbon cloth as an anode material for high-performance supercapacitors.
Guan, Yuzhu; Ji, Peiyuan; Wan, Jing; Zhang, Dazhi; Wang, Zhao; Tian, Hao; Hu, Chenguo; Hu, Baoshan; Tang, Qing; Xi, Yi.
Afiliação
  • Guan Y; Department of Applied Physics, State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing, 400044, People's Republic of China.
Nanotechnology ; 31(12): 125405, 2020 Mar 20.
Article em En | MEDLINE | ID: mdl-31751972
ABSTRACT
By exploiting the storage performance of supercapacitors, iron has the potential to be used as a new anode material. However, this potential is limited by unsatisfactory electrical conductivity and poor cycling stability which impact the energy and power density. Consequently a foundation for improving the electrical conductivity and cycling stability of iron materials to obtain good storage performance is needed. In this work, Ag-modified Fe2O3 nanoparticles on carbon cloth were synthesized as an anode material for supercapacitors. The specific capacitance of the composite material reaches 10.39 F cm-2 (2734.2 F g-1) at a current density of 1 mA cm-2 and remains at 83% of this value after 12 000 cycles. The energy density is 379.8 Wh kg-1 at a power density of 131.6 W kg-1 and remains at 123.9 Wh kg-1 at a power density of 2631.6 W kg-1. The electrical conductivity and interfacial effect created between Ag@Fe2O3 is confirmed with density functional theory calculations. The packaged asymmetric supercapacitor devices have flexibility and can light ten LEDs for 2 min 30 s, with an energy density of 60.3 Wh kg-1 that can be reached at a power density of 1063.8 W kg-1 and remain at 16 Wh kg-1 even at a power density of 4255.3 W kg-1.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2020 Tipo de documento: Article